Using fillers, mixing and handling epoxy is an experience driven set of skills. You can learn a lot from books and web sites (West System has videos), but in the end, you'll only feel comfortable after you've "smoked" a pot or three.
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There's a wide variety of fillers, each with different properties that are added to the epoxy resin. Two primary types are used, adhesive reinforcement fillers and fairing compounds. The adhesive types strengthen the joint, with some being very hard (dense) and others less so. Certain types of bonds will require different fillers. Bonding stainless hardware to a 'glass cover deck for example, compared to a joint where a piece of end grain is involved. The end grain joint will need a "wetter" mixture, that penetrates well and usually with some fibers in it to help the bond. The hardware bond will just require a dense filler material, usually pretty thick that will bridge the gaps.
In most filler applications, you'll use more than one type of filler. An example would be needing a strong adhesive bond on wood to wood joints, but one that doesn't run out of the joint as it cures. I'd use some West System 404 (a high density filler) and some 403 (micro fibers). The 404 makes the joint very strong, but the mixture will tend to sag, so I'd use some 403 to prevent this and create an interlock between the surfaces, because of the fibers in it.
Cab-O-Sil is a product many use as a catch all for their adhesive filler needs. I use it sometimes, but usually mix up my own recipe, depending on what I need the bond to do.
When it comes to fairing compounds, you'll almost always have to mix some thickening agent into the fairing filler. Micro balloons (or spheres) are the typical fairing fillers used. They're literally microscopic hollow balls of 'glass or polyester. This creates a very light weight mixture that is easy to sand, just what you want for fairing large surfaces. It will sag to all get out if used alone, so I'll toss in some silica (West 306) to thicken it up and prevent the sagging. Properly mixed, using the right materials, you can apply thickened epoxy directly overhead and it will not sag, move, drip or run. This takes practice and experience to get right each time you mix a batch up.
I do it by eye and feel as I'm mixing it. I can judge how thick and what material to use from my experience and the "feel" it has as I mix. Some of the epoxy manufactures offer "mixing" guides, which have ratios of different materials for the task. Other manufactures offer pre-mixed resin, which has the fillers in it. This is a costly way of buying epoxy, but can save the trouble of figuring out how to work with fillers.
Generally you'll need enough filler to make the epoxy to at least a "mayonnaise" consistency in a fillet. This will cling to vertical surfaces, but may "creep" slightly during the cure. If you have concerns about this sagging or creeping, then mix it thicker until it's a "peanut butter" like consistency. This will stay put and not sag. As a rule, silica is used to control viscosity, so it doesn't sag or run. You can tell by poking it with a putty knife and pulling up a small chunk. If the thin curly cue on top of the chunk falls over after your knife comes out of the goo, then it's too thin to resist sagging. If the goo "stands" up when you pull your putty knife up through it, then it's thick enough to apply vertically or overhead without worry. You want to error on the too thin side, rather than too thick. You can always add more, but you can't remove any if you've added too much.